Synthesis of amine-modified zeolitic imidazolate framework-8, ultrasound-assisted dye removal and modeling
نویسندگان
چکیده
منابع مشابه
Rapid synthesis of zeolitic imidazolate framework-8 (ZIF-8) nanocrystals in an aqueous system.
We report here the first example of ZIF materials synthesized in aqueous solution. The synthesis was performed at room temperature and typically took several minutes compared to hours and days in non-aqueous conditions. The obtained product were ZIF-8 nanocrystals having size of ~85 nm and showed excellent thermal, hydrothermal and solvothermal stabilities.
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Zeolitic imidazolate frameworks (ZIFs) are a new class of nanoporous compounds which consist of tetrahedral clusters of MN4 (M ) Co, Cu, Zn, etc.) linked by simple imidazolate ligands.1,2 As a subfamily of metal-organic frameworks (MOFs), ZIFs exhibit the tunable pore size and chemical functionality of classical MOFs. At the same time, they possess the exceptional chemical stability and rich st...
متن کاملPorous Proton Exchange Membrane Based Zeolitic Imidazolate Framework-8 (ZIF-8)
Metal-organic frameworks (MOFs) are emerging material class for the past few years due to its tailorability characteristics for various applications. However, the research and development (R&D) of MOFs is still scarce for fuel cell system. This may be due to the several difficulties faced in selecting a good MOFs-based electrolyte, which consequently affects both proton conduction and methanol ...
متن کاملQuasi-free methyl rotation in zeolitic imidazolate framework-8.
Using neutron inelastic scattering and diffraction, we have studied the quantum methyl rotation in zeolitic imidazolate framework-8 (ZIF-8: Zn(MeIM)(2), MeIM = 2-methylimidazolate). The rotational potential for the CH(3) groups in ZIF-8 is shown to be primarily 3-fold in character. The ground-state tunneling transitions at 1.4 K of 334 +/- 1 mueV for CH(3) groups in hydrogenated ZIF-8 (H-ZIF-8)...
متن کاملSurface Modified Cobalt Ferrite Nanoparticles with Cationic Surfactant: Synthesis, Multicomponent Dye Removal Modeling and Selectivity Analysis
Herein, magnetic cobalt ferrite nanoparticles (CFNPs) was synthesized and its surface was modified by cationic surfactant (cetyltrimethyl ammonium bromide: CTAB) and its potential to selective removal of dye from multicomponent (ternary) system was investigated. Direct red 31 (DR31), Direct green 6 (DG6) and Direct red 23 (DR23) were used as a model dyes. The characteristics of the synthesi...
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ژورنال
عنوان ژورنال: Ultrasonics Sonochemistry
سال: 2017
ISSN: 1350-4177
DOI: 10.1016/j.ultsonch.2017.04.030